Macromolecular Metal Carboxylates and Their Nanocomposites
di Gulzhian I. Dzhardimalieva, V. N. Kestelman, Anatolii D. Pomogailo



    Editore: Springer Berlin Heidelberg
    EAN: 9783642264795
    ISBN: 3642264794
    Pagine: 316
    Formato: Paperback

Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and macromolecular metal carboxylates are generalised and described systematically in this monograph. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are also considered.

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